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Octacyanometalate-Based Ferrimagnetic (MMnIII)-Mn-V (M = Mo, W) Bimetallic Chain Racemates with Slow Magnetic Relaxations

Authors
Yoo, Houng SikKo, Hyun HeeRyu, Dae WonLee, Jin WukYoon, Jung HeeLee, Woo RamKim, Hyoung ChanKoh, Eui KwanHong, Chang Seop
Issue Date
6-7월-2009
Publisher
AMER CHEMICAL SOC
Citation
INORGANIC CHEMISTRY, v.48, no.13, pp.5617 - 5619
Indexed
SCIE
SCOPUS
Journal Title
INORGANIC CHEMISTRY
Volume
48
Number
13
Start Page
5617
End Page
5619
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/119681
DOI
10.1021/ic900879d
ISSN
0020-1669
Abstract
Cyanide-bridged M-V-Mn-III (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)(8)](3-) precursors and Wit Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.
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