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ICT-based Cu(II)-sensing 9,10-anthraquinonecalix[4]crown

Authors
Kim, Hyun JungKim, Sang HoonKim, Ja HyungAnh, Le NgocLee, Joung HaeLee, Chang-HeeKim, Jong Seung
Issue Date
10-6월-2009
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
ICT; Chromogenic; Anthraquinone; Calixarenes; Copper ion
Citation
TETRAHEDRON LETTERS, v.50, no.23, pp.2782 - 2786
Indexed
SCIE
SCOPUS
Journal Title
TETRAHEDRON LETTERS
Volume
50
Number
23
Start Page
2782
End Page
2786
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/119829
DOI
10.1016/j.tetlet.2009.03.149
ISSN
0040-4039
Abstract
A series of calix[4]arene-based chromogenic sensors bearing the 9,10-anthraquinone moiety have been synthesized and examined for their abilities to recognize various cations such as Li+, Na+, K+, Rb+, Cs+, Ag+, Cd2+ Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Hg2+, Pb2+, Co2+, and Cu2+ by UV-vis spectroscopy. In acetonitrile, the presence of Cu2+ induces the formation of the 1:1 ligand/metal complex, which exhibits a new absorption band centered at 450 nm, and leads to an obvious color change from yellow to red. (C) 2009 Elsevier Ltd. All rights reserved.
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