Structural and magnetic properties of chemically synthesized Fe doped ZnO

Abstract

We report on the synthesis of Fe-doped ZnO with nominal composition of Zn0.99Fe0.01O by using a coprecipitation method. X-ray diffraction and selective area electron diffraction studies reveal a single phase wurtzite crystal structure without any secondary phase. Field emission transmission electron microscopy measurements infer that Zn0.99Fe0.01O have nanorod-type microstructures. Magnetic hysteresis measurement performed at different temperatures show that Zn0.99Fe0.01O exhibits a weak ferromagnetic behavior at room temperature. A detailed investigation of the electronic and local structure using O K-, Fe L-3,L-2 near edge x-ray absorption fine structure suggests that Fe is substituting Zn in ZnO matrix and is in Fe3+ state. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3073933]