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Cyanide-Bridged One-Dimensional Ferromagnetic (RuMnIII)-Mn-III Coordination Polymer Exhibiting a Field-Induced Magnetic Phase Transition
- Authors
- Yoon, Jung Hee; Yoo, Houng Silk; Kim, Hyoung Chan; Yoon, Sung Won; Suh, Byoung Jin; Hong, Chang Seop
- Issue Date
- 2-2월-2009
- Publisher
- AMER CHEMICAL SOC
- Citation
- INORGANIC CHEMISTRY, v.48, no.3, pp.816 - 818
- Indexed
- SCIE
SCOPUS
- Journal Title
- INORGANIC CHEMISTRY
- Volume
- 48
- Number
- 3
- Start Page
- 816
- End Page
- 818
- ISSN
- 0020-1669
- Abstract
- A cyanide-linked Ru-III(4d)-Mn-III(3d) bimetallic chain complex (1) was prepared by the self-assembly of a ruthenium(III) bicyanide and a Mn-III Schiff base. Ferromagnetic couplings between the magnetic centers are present within a chain, while antiferromagnetic interactions between chains (T-N = 2.5 K) transmit. Complex 1 also shows a field-induced magnetic phase transition.
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