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Kinetic Resolutions by Enantioselective Pauson-Khand-Type Reaction
- Authors
- Kim, Dong Eun; Kwak, Jaesung; Kim, In Su; Jeong, Nakcheol
- Issue Date
- 1월-2009
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- allyl propargyl ethers; atropisomerism; iridium; kinetic resolution; Pauson-Khand reaction; rhodium
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, v.351, no.1-2, pp.97 - 102
- Indexed
- SCIE
SCOPUS
- Journal Title
- ADVANCED SYNTHESIS & CATALYSIS
- Volume
- 351
- Number
- 1-2
- Start Page
- 97
- End Page
- 102
- ISSN
- 1615-4150
- Abstract
- A kinetic resolution of 1-arylallyl propargyl ethers by enantioselective Pauson-Khand-type reaction catalysts was successfully carried out. While cationic rhodium(I) with a BINAP-based ligand having an electron-deficient phosphine is the choice for the slow reacting substrates, neutral iridium(I) with a BINAP-based ligand possessing an electron-rich phosphine provided excellent results for the more reactive substrates.
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