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Easy synthesis and characterization of single-crystalline hexagonal prism-shaped hematite alpha-Fe2O3 in aqueous media

Authors
Chaudhari, Nitin KadubaKim, Hyoung ChanSon, DeracYu, Jong-Sung
Issue Date
2009
Publisher
ROYAL SOC CHEMISTRY
Keywords
hexagonal prism; hematite; Fe2O3; magnetic materials
Citation
CRYSTENGCOMM, v.11, no.11, pp.2264 - 2267
Indexed
SCIE
SCOPUS
Journal Title
CRYSTENGCOMM
Volume
11
Number
11
Start Page
2264
End Page
2267
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/120901
DOI
10.1039/b910569g
ISSN
1466-8033
Abstract
A simple, mild and environmentally friendly one-pot aqueous synthesis route using urea devoid of surfactant and chelating agents is demonstrated for the first time to fabricate high yield crystalline uniform hexagonal prism-shaped weakly magnetic alpha-Fe2O3 nanocrystals. As synthesized alpha-Fe2O3 nanocrystals show ferromagnetic behavior with coercivity values of 0.8 and 0.2 T at 5 and 300 K, respectively. The urea and reaction temperature plays a crucial role, regulating the morphology and the size.
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