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Synthesis of 5-ortho-Carboranylsalicylaldehyde and an Indolinospirobenzopyran

Authors
Lee, Seung HwanKwon, Young BumYoon, Cheol Min
Issue Date
2009
Publisher
TAYLOR & FRANCIS INC
Keywords
Coumarin; indolinospirobenzopyran; ortho-carborane; salicylaldehyde
Citation
SYNTHETIC COMMUNICATIONS, v.39, no.22, pp.4069 - 4078
Indexed
SCIE
SCOPUS
Journal Title
SYNTHETIC COMMUNICATIONS
Volume
39
Number
22
Start Page
4069
End Page
4078
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/122126
DOI
10.1080/00397910902883694
ISSN
0039-7911
Abstract
5-ortho-Carboranylsalicylaldehyde was prepared from 5-iodosalicylaldehyde in six steps in 18% overall yield, and also from 5-iodosalicylic acid in seven steps in 45% overall yield. The reaction of 5-ortho-carboranylsalicylaldehyde with Fischer's base gave a spiropyran in 63% yield.
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