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Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature
- Authors
- Kim, Dong Eun; Kim, In Su; Ratovelomanana-Vidal, Virginie; Genet, Jean-Pierre; Jeong, Nakcheol
- Issue Date
- 17-10월-2008
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF ORGANIC CHEMISTRY, v.73, no.20, pp.7985 - 7989
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 73
- Number
- 20
- Start Page
- 7985
- End Page
- 7989
- ISSN
- 0022-3263
- Abstract
- An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC(4)H(4)-BINAP ligand at 18-20 degrees C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.
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