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Bulk heterojunction organic photovoltaic cell fabricated with a p-type conjugated star-shaped molecule

Authors
Lee, Tae WanKim, Dae CheolKang, Nam SuYu, Jae WoongCho, Min JuKim, Kyung HwanChoi, Dong Hoon
Issue Date
5-8월-2008
Publisher
CHEMICAL SOC JAPAN
Citation
CHEMISTRY LETTERS, v.37, no.8, pp.866 - 867
Indexed
SCIE
SCOPUS
Journal Title
CHEMISTRY LETTERS
Volume
37
Number
8
Start Page
866
End Page
867
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/122873
DOI
10.1246/cl.2008.866
ISSN
0366-7022
Abstract
A new multibranched crystalline Molecule was synthesized through Horner-Emmons reactions Using hexyl-substituted thiophene-based carbaldehydes as dendrons and benzene-1,2,4,5-tetramethylphosphonic acid octaethyl ester its the core unit. The molecule was employed to fabricate organic photovoltaic (OPV) cells with methanofullerene [6.6]-phenyl C61-butyric acid methyl ester (PCBM). Poly(3-hexylthiophene) (P3HT) wits also used its a dopant to improve the film quality and power conversion efficiency. As a result, the short-circuit current density and open Circuit voltage were increased when P3HT was added into 4(HPBT) and PCBM dyad. resulting in a hi,,her power conversion efficiency of around 0.6%.
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