Cu2+-induced intermolecular static excimer formation of pyrenealkylamine
- Authors
- Kim, Hyun Jung; Hong, Jooyeon; Hong, Areum; Ham, Sihyun; Lee, Joung Hae; Kim, Jong Seung
- Issue Date
- 15-5월-2008
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.10, no.10, pp.1963 - 1966
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC LETTERS
- Volume
- 10
- Number
- 10
- Start Page
- 1963
- End Page
- 1966
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/123535
- DOI
- 10.1021/ol800475d
- ISSN
- 1523-7060
- Abstract
- Synthesis of monopyrenylalkylamine derivative 1 and its fluorescence behavior for Cu2+ in H2O/CH3CN (1:1, v/v) were investigated. Upon Cu2+ binding, 1, bearing a sulfonamide group, exhibited a marked excimer emission at 455 nm along with a weak monomer emission at 375 nm. The excimer emission, driven by formation of an intermolecular pyrenyl static excimer upon Cu2+ binding to the sulfonamide group, is rationalized by experimental and theoretical DFT calculation results.
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