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Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units
- Issue Date
- 20-3월-2008
- Publisher
- KOREAN CHEMICAL SOC
- Keywords
- calixarene; thiacalixarene; strontium; voltammetry; ion recognition
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.29, no.3, pp.620 - 622
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 29
- Number
- 3
- Start Page
- 620
- End Page
- 622
- ISSN
- 0253-2964
- Abstract
- A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.
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Collections - College of Science > Department of Chemistry > 1. Journal Articles
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