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Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units

Authors
Kim, Tae HyunKim, HasuckLee, Joung HaeKim, Jong Seung
Issue Date
20-3월-2008
Publisher
KOREAN CHEMICAL SOC
Keywords
calixarene; thiacalixarene; strontium; voltammetry; ion recognition
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.29, no.3, pp.620 - 622
Indexed
SCIE
SCOPUS
KCI
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume
29
Number
3
Start Page
620
End Page
622
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/123884
ISSN
0253-2964
Abstract
A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.
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