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Structure and magnetic properties of cyanide-bridged (Ni9Mo6V)-Mo-II cluster modified by bidentate capping ligands

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dc.contributor.authorLim, Jung Hak-
dc.contributor.authorYoo, Houng Sik-
dc.contributor.authorYoon, Jung Hee-
dc.contributor.authorKoh, Eui Kwan-
dc.contributor.authorKim, Hyoung Chan-
dc.contributor.authorHong, Chang Seop-
dc.date.accessioned2021-09-09T11:58:39Z-
dc.date.available2021-09-09T11:58:39Z-
dc.date.created2021-06-15-
dc.date.issued2008-01-20-
dc.identifier.issn0277-5387-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/124219-
dc.description.abstractA cyanide-bridged Ni9Mo6 cluster (1) capped with chelating bidentate ligands was prepared by self-assembling [Mo(CN)(8)](3-), Ni2+, and bipyridine in a stoichiometric ratio. Compound I crystallized in the triclinic system with space group P! shows a body-centered Ni cube capped with six Mo entities. The non-covalent pi-pi stackings present in I lead to the extension of the molecule to a 2D sheet. Magnetic data exhibit that intracluster ferromagnetic interactions in 1 are operative through the CN linkage coupled with zero-field splitting of the cluster with an S = 12 ground state. (C) 2007 Elsevier Ltd. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectSINGLE-MOLECULE MAGNETISM-
dc.subjectHIGH-SPIN MOLECULES-
dc.subjectINTERMOLECULAR INTERACTIONS-
dc.subjectBUILDING-BLOCK-
dc.subjectMN-II-
dc.subjectMO-
dc.subjectRELAXATION-
dc.subjectCOMPLEXES-
dc.subjectSYMMETRY-
dc.subjectBEHAVIOR-
dc.titleStructure and magnetic properties of cyanide-bridged (Ni9Mo6V)-Mo-II cluster modified by bidentate capping ligands-
dc.typeArticle-
dc.contributor.affiliatedAuthorHong, Chang Seop-
dc.identifier.doi10.1016/j.poly.2007.09.006-
dc.identifier.scopusid2-s2.0-37349030832-
dc.identifier.wosid000253191100038-
dc.identifier.bibliographicCitationPOLYHEDRON, v.27, no.1, pp.299 - 303-
dc.relation.isPartOfPOLYHEDRON-
dc.citation.titlePOLYHEDRON-
dc.citation.volume27-
dc.citation.number1-
dc.citation.startPage299-
dc.citation.endPage303-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaCrystallography-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.relation.journalWebOfScienceCategoryCrystallography-
dc.subject.keywordPlusSINGLE-MOLECULE MAGNETISM-
dc.subject.keywordPlusHIGH-SPIN MOLECULES-
dc.subject.keywordPlusINTERMOLECULAR INTERACTIONS-
dc.subject.keywordPlusBUILDING-BLOCK-
dc.subject.keywordPlusMN-II-
dc.subject.keywordPlusMO-
dc.subject.keywordPlusRELAXATION-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusSYMMETRY-
dc.subject.keywordPlusBEHAVIOR-
dc.subject.keywordAuthornickel-
dc.subject.keywordAuthormolybdenum-
dc.subject.keywordAuthorcluster compounds-
dc.subject.keywordAuthormagnetic properties-
dc.subject.keywordAuthorcyanides-
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