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Structure and magnetic properties of cyanide-bridged (Ni9Mo6V)-Mo-II cluster modified by bidentate capping ligands
- Authors
- Lim, Jung Hak; Yoo, Houng Sik; Yoon, Jung Hee; Koh, Eui Kwan; Kim, Hyoung Chan; Hong, Chang Seop
- Issue Date
- 20-1월-2008
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- nickel; molybdenum; cluster compounds; magnetic properties; cyanides
- Citation
- POLYHEDRON, v.27, no.1, pp.299 - 303
- Indexed
- SCIE
SCOPUS
- Journal Title
- POLYHEDRON
- Volume
- 27
- Number
- 1
- Start Page
- 299
- End Page
- 303
- ISSN
- 0277-5387
- Abstract
- A cyanide-bridged Ni9Mo6 cluster (1) capped with chelating bidentate ligands was prepared by self-assembling [Mo(CN)(8)](3-), Ni2+, and bipyridine in a stoichiometric ratio. Compound I crystallized in the triclinic system with space group P! shows a body-centered Ni cube capped with six Mo entities. The non-covalent pi-pi stackings present in I lead to the extension of the molecule to a 2D sheet. Magnetic data exhibit that intracluster ferromagnetic interactions in 1 are operative through the CN linkage coupled with zero-field splitting of the cluster with an S = 12 ground state. (C) 2007 Elsevier Ltd. All rights reserved.
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