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Nuclear Magnetic Relaxation Study of the Organic-Inorganic Hybrid Systems (CnH2n+1NH3)2SnCl6Nuclear Magnetic Relaxation Study of the Organic-Inorganic Hybrid Systems (CnH2n+1NH3)2SnCl6

Other Titles
Nuclear Magnetic Relaxation Study of the Organic-Inorganic Hybrid Systems (CnH2n+1NH3)2SnCl6
Authors
이규원이철의
Issue Date
2005
Publisher
한국자기학회
Keywords
Nuclear magnetic relaxation; Organic-inorganic hybrid systems; Phase transitio; Nuclear magnetic relaxation; Organic-inorganic hybrid systems; Phase transitio
Citation
Journal of Magnetics, v.10, no.2, pp.63 - 65
Indexed
KCI
Journal Title
Journal of Magnetics
Volume
10
Number
2
Start Page
63
End Page
65
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/126053
ISSN
1226-1750
Abstract
The 1H NMR spin-lattice relaxation in a series of the organic-inorganic hybrid systems (n-CnH2n+1NH3)2SnCl6 (n=10, 12, 14) undergoingtwo successive phase transitions was studied. A discontinuity characteristic of a first order phase transition was observed at the high-temperature conformational transition. Besides, the spin-lattice relaxation rate below the conformational transition temperature was well fitted by four types of molecular motions, from which the chain-length dependence of the activation energies of the molecular groups was obtained.
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