Increasing sulfur utilization in lithium-sulfur batteries by a Co-MOF-74@MWCNT interlayer
- Authors
- Sung, S.; Kim, B.H.; Lee, S.; Choi, S.; Yoon, W.Y.
- Issue Date
- 9월-2021
- Publisher
- Elsevier B.V.
- Keywords
- Co-MOF-74; Interlayer; Li-S battery; Shuttling effect; Sulfur utilization
- Citation
- Journal of Energy Chemistry, v.60, pp.186 - 193
- Indexed
- SCIE
SCOPUS
- Journal Title
- Journal of Energy Chemistry
- Volume
- 60
- Start Page
- 186
- End Page
- 193
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/128657
- DOI
- 10.1016/j.jechem.2020.12.033
- ISSN
- 2095-4956
- Abstract
- To improve lithium-sulfur battery performance, Co-MOF-74 has been applied for the first time as an interlayer with multiwalled carbon nanotubes (MWCNTs). Co-MOF-74@MWCNT was synthesized using a solvothermal method. The fabrication of Co-MOF-74@MWCNT was confirmed by scanning electron microscopy, X-ray diffraction, thermogravimetric analysis, and Brunauer-Emmett-Teller testing. The interlayer was fabricated using a filtration method. Assembled batteries were prepared using a Co-MOF-74@MWCNT interlayer and an MWCNT interlayer and subsequently investigated via cyclic voltammetry tests. Co-MOF-74 promotes a redox reaction and shows a small peak at 1.85 V. A symmetric and full cell test revealed that the Co-MOF-74@MWCNT cell enables a faster redox reaction and higher capacity than that of the MWCNT cell. After 15 cycles, the Co-MOF-74@MWCNT cell achieved a value of 1112 mAh g−1, which is 26% greater than that of the MWCNT cell (880 mAh g−1) at 0.2C. Voltage profile testing showed that the reason for the higher capacity of the Co-MOF-74@MWCNT cell is that it promotes the conversion of Li2S2 to Li2S. Various electrochemical analyses confirmed that the Co-MOF-74@MWCNT interlayer acts not only as a physical and chemical barrier but also promotes the transformation of Li2S2 to Li2S. © 2021 Science Press
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