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Palladium-Catalyzed Oxidative Aminocarbonylation by Decarboxylative Coupling: Synthesis of Alkynyl Amides
- Issue Date
- 4월-2015
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Synthetic methods; Palladium; Carbonylation; Alkynes; Amides
- Citation
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2015, no.10, pp.2235 - 2243
- Indexed
- SCIE
SCOPUS
- Journal Title
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 2015
- Number
- 10
- Start Page
- 2235
- End Page
- 2243
- ISSN
- 1434-193X
- Abstract
- Alkynyl amides were synthesized from a palladium-catalyzed coupling reaction of alkynyl carboxylic acids and amines under carbon monoxide. The reaction was conducted with palladium(II) acetate (5 mol-%) and silver(I) oxide (1.0 equiv.) in acetonitrile at 80 degrees C for 1 h. This method provides good to moderate product yields and good functional group tolerance towards ketone, ester, and nitrile groups.
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