Harnessing visible-light energy for unbiased organic photoelectrocatalysis: synthesis of N-bearing fused rings
- Authors
- Gong, Ming; Huang, Mengmeng; Li, Yabo; Zhang, Jianye; Kim, Jung Keun; Kim, Jong Seung; Wu, Yangjie
- Issue Date
- 24-1월-2022
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- GREEN CHEMISTRY, v.24, no.2, pp.837 - 845
- Indexed
- SCIE
SCOPUS
- Journal Title
- GREEN CHEMISTRY
- Volume
- 24
- Number
- 2
- Start Page
- 837
- End Page
- 845
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/136517
- DOI
- 10.1039/d1gc03587h
- ISSN
- 1463-9262
- Abstract
- In this research, we realized the conversion of visible light to electrical energy and C-H activation by the synergistic catalytic effect of visible-light and photoelectric current. An atom-economical and environment-friendly self-biasing interfacial photo-electrocatalytic method for cascade C-H activation/cyclization is provided to construct N-containing fused ring compounds using an m-BiVO4 film as a photoanode. There are obvious advantages of this transformation due to no external bias and a small overpotential, saving electrical energy and avoiding excessive oxidation of malononitrile to achieve better chemical reactivity and selectivity. Meanwhile, the recovered photoanode could be used more than ten times.
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Collections - College of Science > Department of Chemistry > 1. Journal Articles
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