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Heterocyclic Mechanophores in Polymer Mechanochemistry

Authors
Jung, SangminYoon, Hyo Jae
Issue Date
Jun-2022
Publisher
GEORG THIEME VERLAG KG
Keywords
mechanochemistry; heterocycles; polymers; mechanophores; forces; ultrasonication; reaction mechanisms
Citation
SYNLETT, v.33, no.9, pp.863 - 874
Indexed
SCIE
SCOPUS
Journal Title
SYNLETT
Volume
33
Number
9
Start Page
863
End Page
874
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/137591
DOI
10.1055/a-1703-2608
ISSN
0936-5214
Abstract
This Account covers the recent progress made on heterocyclic mechanophores in the field of polymer mechanochemistry. In particular, the types of such mechanophores as well as the mechanisms and applications of their force-induced structural transformations are discussed and related perspectives and future challenges proposed. 1 Introduction 2 Types of Mechanophores 3 Methods to Incorporate Heterocycle Mechanophores into Polymer Systems 4 Mechanochemical Reactions of Heterocyclic Mechanophores 4.1 Three-Membered-Ring Mechanophores 4.2 Four-Membered-Ring Mechanophores 4.3 Six-Membered-Ring Mechanophores 4.4 Bicyclic Mechanophores 5 Applications 5.1 Cross-Linking of Polymer 5.2 Degradable Polymer 5.3 Mechanochromic Polymer 6 Concluding Remarks and Outlook © 2021. Thieme. All rights reserved.
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