Solvation structure of phosphonium ionic liquid/CH3SCN mixture as electrolytes for Li-ion batteries: Infrared pump-probe spectroscopic studies
DC Field | Value | Language |
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dc.contributor.author | Sahu, Prabhat Kumar | - |
dc.contributor.author | Kim, Jungyu | - |
dc.contributor.author | Park, Kwanghee | - |
dc.contributor.author | Kim, Eunchan | - |
dc.contributor.author | Mondal, Saptarsi | - |
dc.contributor.author | Kwak, Kyungwon | - |
dc.contributor.author | Cho, Minhaeng | - |
dc.date.accessioned | 2022-04-02T10:40:22Z | - |
dc.date.available | 2022-04-02T10:40:22Z | - |
dc.date.created | 2022-04-01 | - |
dc.date.issued | 2022-02 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/139505 | - |
dc.description.abstract | Lithium-ion battery (LIB) electrolytes based on room-temperature ionic liquids (RTIL) are promising as safe and sustainable LIB electrolytes. However, there are no reports on the solvation structure and dynamics of RTIL due to the existence of various solvation species in RTIL. Here, we investigated the solvation structure and dynamics of binary mixtures of the phosphonium ionic liquid, tributyl(2-methoxyethyl)phosphonium bis(trifluoromethanesulfonyl)imide (P444102TFSI), and methylthiocyanate (CH3SCN), with ultrafast mid-IR Spectroscopy. The changes of vibrational and rotational dynamics of CH3SCN center dot center dot center dot Li+ complex and free CH3SCN with an increase in CH3SCN concentration suggest the presence of at least four solvation species, providing superior resolving power for various solvation species existing in complex LIB electrolytes. Our experimental results show that the environment of free CH3SCN and CH3SCN center dot center dot center dot Li+ complex changes drastically with change in CH3SCN mole fraction and Li salt concentration in the mixture. We expect that this can affect the Li-ion transport mechanism in the IL-based electrolytes. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | ELECTROCHEMICAL PROPERTIES | - |
dc.subject | LIQUID ELECTROLYTES | - |
dc.subject | ENERGY | - |
dc.subject | DYNAMICS | - |
dc.title | Solvation structure of phosphonium ionic liquid/CH3SCN mixture as electrolytes for Li-ion batteries: Infrared pump-probe spectroscopic studies | - |
dc.title.alternative | Solvation structure of phosphonium ionic liquid/CH3SCN mixture as electrolytes for Li-ion batteries: Infrared pump-probe spectroscopic studies | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kwak, Kyungwon | - |
dc.contributor.affiliatedAuthor | Cho, Minhaeng | - |
dc.identifier.doi | 10.1002/bkcs.12463 | - |
dc.identifier.scopusid | 2-s2.0-85122036351 | - |
dc.identifier.wosid | 000734947300001 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.43, no.2, pp.215 - 221 | - |
dc.relation.isPartOf | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 43 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 215 | - |
dc.citation.endPage | 221 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART002811534 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | ELECTROCHEMICAL PROPERTIES | - |
dc.subject.keywordPlus | LIQUID ELECTROLYTES | - |
dc.subject.keywordPlus | ENERGY | - |
dc.subject.keywordPlus | DYNAMICS | - |
dc.subject.keywordAuthor | contact ion pair | - |
dc.subject.keywordAuthor | electrolytes | - |
dc.subject.keywordAuthor | ionic liquid | - |
dc.subject.keywordAuthor | pump-probe experiments | - |
dc.subject.keywordAuthor | solvation species | - |
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