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Solvation structure of phosphonium ionic liquid/CH3SCN mixture as electrolytes for Li-ion batteries: Infrared pump-probe spectroscopic studiesSolvation structure of phosphonium ionic liquid/CH3SCN mixture as electrolytes for Li-ion batteries: Infrared pump-probe spectroscopic studies

Other Titles
Solvation structure of phosphonium ionic liquid/CH3SCN mixture as electrolytes for Li-ion batteries: Infrared pump-probe spectroscopic studies
Authors
Sahu, Prabhat KumarKim, JungyuPark, KwangheeKim, EunchanMondal, SaptarsiKwak, KyungwonCho, Minhaeng
Issue Date
2월-2022
Publisher
WILEY-V C H VERLAG GMBH
Keywords
contact ion pair; electrolytes; ionic liquid; pump-probe experiments; solvation species
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.43, no.2, pp.215 - 221
Indexed
SCIE
SCOPUS
KCI
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume
43
Number
2
Start Page
215
End Page
221
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/139505
DOI
10.1002/bkcs.12463
ISSN
0253-2964
Abstract
Lithium-ion battery (LIB) electrolytes based on room-temperature ionic liquids (RTIL) are promising as safe and sustainable LIB electrolytes. However, there are no reports on the solvation structure and dynamics of RTIL due to the existence of various solvation species in RTIL. Here, we investigated the solvation structure and dynamics of binary mixtures of the phosphonium ionic liquid, tributyl(2-methoxyethyl)phosphonium bis(trifluoromethanesulfonyl)imide (P444102TFSI), and methylthiocyanate (CH3SCN), with ultrafast mid-IR Spectroscopy. The changes of vibrational and rotational dynamics of CH3SCN center dot center dot center dot Li+ complex and free CH3SCN with an increase in CH3SCN concentration suggest the presence of at least four solvation species, providing superior resolving power for various solvation species existing in complex LIB electrolytes. Our experimental results show that the environment of free CH3SCN and CH3SCN center dot center dot center dot Li+ complex changes drastically with change in CH3SCN mole fraction and Li salt concentration in the mixture. We expect that this can affect the Li-ion transport mechanism in the IL-based electrolytes.
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