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Capture and detection of SO2 using a chemically stable Mg(ii)-MOF

Authors
Martinez-Ahumada, EvaKim, Dae WonWahiduzzaman, MohammadCarmona-Monroy, PaulinaLopez-Olvera, AlfredoWilliams, Daryl R.Martis, VladimirLara-Garcia, Hugo A.Lopez-Morales, S.Solis-Ibarra, DiegoMaurin, GuillaumeIbarra, Ilich A.Hong, Chang Seop
Issue Date
20-9월-2022
Publisher
ROYAL SOC CHEMISTRY
Citation
JOURNAL OF MATERIALS CHEMISTRY A, v.10, no.36, pp.18636 - 18643
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF MATERIALS CHEMISTRY A
Volume
10
Number
36
Start Page
18636
End Page
18643
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/145739
DOI
10.1039/d2ta04842f
ISSN
2050-7488
Abstract
The MOF-type Mg-2(dobpdc) shows a record high capacity for SO2 capture (19.5 mmol g(-1) at 298 K and up to 1 bar), high chemical stability towards dry and humid SO2 and an outstanding cycling performance with facile regeneration. Advanced molecular simulations have been coupled to gain insight into the molecular mechanisms responsible for the high adsorption of SO2. Fluorescence experiments further demonstrated the SO2 detection properties of this MOF material.
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