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Cited 3 time in webofscience Cited 3 time in scopus
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Metal-Organic Framework Adsorbent for Practical Capture of Trace Carbon Dioxide

Authors
Park, JinkyoungPark, Jeoung RyulChoe, Jong HyeakKim, SaemiKang, MinjungKang, Dong WonKim, Jee YeonJeong, Yong WonHong, Chang Seop
Issue Date
11-Nov-2020
Publisher
AMER CHEMICAL SOC
Keywords
metal-organic framework; indoor air capture; amine functionalization; PDMS coating; ultra-microproliferation
Citation
ACS APPLIED MATERIALS & INTERFACES, v.12, no.45, pp.50534 - 50540
Indexed
SCIE
SCOPUS
Journal Title
ACS APPLIED MATERIALS & INTERFACES
Volume
12
Number
45
Start Page
50534
End Page
50540
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/51815
DOI
10.1021/acsami.0c16224
ISSN
1944-8244
Abstract
Control of indoor CO2 concentration to a safe level is important to human health. Metal-organic-framework-based adsorbents show superior adsorption performance at moderate CO2 concentration compared to other solid adsorbents but suffer from low capacities and high regeneration temperature at indoor CO2 concentrations and poor humidity stability. Herein, we report epn-grafted Mg-2(dobpdc) (epn = 1-ethylpropane-1,3-diamine) showing a CO2 capacity of 12.2 wt % at an acceptable concentration of 1000 ppm and a practically low desorption temperature of 70 degrees C, which surpasses the performance of conventional solid adsorbents under the given conditions. After poly(dimethylsiloxane) coating, this material reveals a significant adsorption amount (similar to 10 wt %) in humid conditions (up to 98% relative humidity) with structural durability.
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