Force-Induced Cycloaddition of Aziridine: Can We Force a New Route?
- Authors
- Jung, Sangmin; Kim, Seo Yeon; Yoon, Hyo Jae
- Issue Date
- 1-9월-2020
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- aziridines; cycloaddition; mechanochemistry; mechanophores; stereoselectivity
- Citation
- SYNLETT, v.31, no.14, pp.1343 - 1348
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNLETT
- Volume
- 31
- Number
- 14
- Start Page
- 1343
- End Page
- 1348
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/53213
- DOI
- 10.1055/s-0040-1707145
- ISSN
- 0936-5214
- Abstract
- Cycloaddition reactions of aziridines with dipolarophiles under traditional thermal or photochemical conditions entail destructive routes to form reactive intermediates such as an azomethine ylide. This article highlights a recent study that demonstrates a cycloaddition reaction of aziridine induced by mechanical force. Experimental results suggest that the force-induced cycloaddition of aziridine with dimethyl acetylenedicarboxylate as a dipolarophile does not seem to involve an ylide, with implications for a possible new reaction route. 1 Rivalry between Aziridine and Epoxide 2 Mechanochemically Responsive Polymers 3 Aziridine Mechanophore 4 Concluding Remarks and Outlook
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Science > Department of Chemistry > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.