Supramolecular Tubule from Seesaw Shaped Amphiphile and Its Hierarchical Evolution into Sheet
DC Field | Value | Language |
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dc.contributor.author | Sun, Haonan | - |
dc.contributor.author | Dong, Longlong | - |
dc.contributor.author | Kim, Yongju | - |
dc.contributor.author | Lee, Myongsoo | - |
dc.date.accessioned | 2021-08-30T16:50:26Z | - |
dc.date.available | 2021-08-30T16:50:26Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2020-08-17 | - |
dc.identifier.issn | 1861-4728 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/53753 | - |
dc.description.abstract | Although supramolecular one-dimensional (1D) and two-dimensional (2D) structures with various unique properties have been extensively studied, the reversible switching between tubules and sheets via lateral association remains challenging. Here, we report the unique structures of a supramolecular tubular bamboo culm in which the hollow-tubular interior is separated, at intervals, by nodes per 1.3 nm. Interestingly, the discrete tubules are able to hierarchically assemble into a flat sheet in response to an aromatic guest. The addition oftrans-azobenzene, as a guest, enables the tubules to form a hierarchical sheet assembly via the lateral interaction. The hierarchical sheet structures are disassembled into their constituent tubules upon UV irradiation due totrans-cisisomerization. The recovery fromcis-azobenzene totrans-form induces repeatedly the hierarchical sheet assembly, indicative of a reversible switching behavior between tubules and sheets triggered by an external stimulus. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | NANOFIBERS | - |
dc.subject | MICELLES | - |
dc.title | Supramolecular Tubule from Seesaw Shaped Amphiphile and Its Hierarchical Evolution into Sheet | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Yongju | - |
dc.identifier.doi | 10.1002/asia.202000654 | - |
dc.identifier.scopusid | 2-s2.0-85087831762 | - |
dc.identifier.wosid | 000548274900001 | - |
dc.identifier.bibliographicCitation | CHEMISTRY-AN ASIAN JOURNAL, v.15, no.16, pp.2470 - 2474 | - |
dc.relation.isPartOf | CHEMISTRY-AN ASIAN JOURNAL | - |
dc.citation.title | CHEMISTRY-AN ASIAN JOURNAL | - |
dc.citation.volume | 15 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 2470 | - |
dc.citation.endPage | 2474 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | NANOFIBERS | - |
dc.subject.keywordPlus | MICELLES | - |
dc.subject.keywordAuthor | Seesaw-Shaped Amphiphile | - |
dc.subject.keywordAuthor | Tubular Culm | - |
dc.subject.keywordAuthor | Supramolecule | - |
dc.subject.keywordAuthor | Lateral Association | - |
dc.subject.keywordAuthor | Sheet | - |
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