Supramolecular Tubule from Seesaw Shaped Amphiphile and Its Hierarchical Evolution into Sheet

Abstract

Although supramolecular one-dimensional (1D) and two-dimensional (2D) structures with various unique properties have been extensively studied, the reversible switching between tubules and sheets via lateral association remains challenging. Here, we report the unique structures of a supramolecular tubular bamboo culm in which the hollow-tubular interior is separated, at intervals, by nodes per 1.3 nm. Interestingly, the discrete tubules are able to hierarchically assemble into a flat sheet in response to an aromatic guest. The addition oftrans-azobenzene, as a guest, enables the tubules to form a hierarchical sheet assembly via the lateral interaction. The hierarchical sheet structures are disassembled into their constituent tubules upon UV irradiation due totrans-cisisomerization. The recovery fromcis-azobenzene totrans-form induces repeatedly the hierarchical sheet assembly, indicative of a reversible switching behavior between tubules and sheets triggered by an external stimulus.