Heteroatom and Crystallinity-Controlled Carbon Felts Based on Silk for Li-TEMPO Redox Flow Battery
- Authors
- Yoon, Seung Uk; Jung, Ji In; Yun, Young Soo; Jin, Hyoung-Joon
- Issue Date
- 7월-2020
- Publisher
- POLYMER SOC KOREA
- Keywords
- silk; carbon felt; redox flow battery; 2,2,6,6-tetramethylpiperidine-loxyl (TEMPO); heteroatom
- Citation
- POLYMER-KOREA, v.44, no.4, pp.542 - 548
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- POLYMER-KOREA
- Volume
- 44
- Number
- 4
- Start Page
- 542
- End Page
- 548
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/54884
- DOI
- 10.7317/pk.2020.44.4.542
- ISSN
- 0379-153X
- Abstract
- Silk fiber, a precursor rich in heteroatom, was heat-treated at various temperatures from 800 to 2800 degrees C to prepare carbon felts that have different heteroatom contents and carbon microstructures. With the heat treatment temperatures, the heteroatom contents of the silk-derived carbon felts (SCFs) gradually decreased, their graphitic carbon structures were continuously developed, and their electrical conductivities were linearly improved. By comparing with electrochemical reactivities of SCFs as an electrode in the lithim-2,2,6,6-tetramethylpiperidine-loxyl (Li-TEMPO) redox flow battery (Li-TEMPO RFB) system, it was found that a redox potential separation of the SCFs heat-treated at 2800 degrees C (SCF2800) was reduced by similar to 61 mV at 10 mV s(-1) compared with the SCF heat-treated at 800 degrees C (SCF800). In addition, in a galvanostatic charge/discharge tests at current densities from 0.1 to 2 mA g(-1), the capacity retention of SCF2800 is similar to 24% higher than that of SCF800. Moreover, in an impedance resistance measurement, the charge transfer resistance of SCF2800 which occurs in an interface between electrolyte and electrodes was much lower than that of SCF800. These results provide that the electrical conductivity of electrode materials is the key on the electrochemical performances of Li-TEMPO RFBs which is much more significant than the catalytic effect of heteroatoms on the surface of electrode materials.
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Collections - Graduate School > KU-KIST Graduate School of Converging Science and Technology > 1. Journal Articles
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