Nanostructured chitosan/molecular sieve-4A an emergent material for the synergistic adsorption of radioactive major pollutants cesium and strontium

Abstract

A fresh adsorbent nanostructured chitosan/molecular sieve 4A hybrid (NSC@MS-4A) was fabricated for the rapid adsorption of strontium (Sr2+) and cesium (Cs+ ) ions from aqueous solutions. The as-obtained NSC@MS-4A were thoroughly characterized by XRD, FE-SEM, EDS, BET, XPS and FT-IR. The physio-chemical properties and structural aspects revealed that NSC@MS-4A acquires fine surface area (72 m(2)/g), porous structure as well as compatible functional groups (-P-O-P and -C-O-C) for the admission of Cs+ and Sr2+ ions. The batch adsorption studies concluded that prepared adsorbent displayed a maximum adsorption of 92-94 % within 40 min. Fast adsorption of Cs+ and Sr2+ was achieved at neutral pH (6-7), ambient temperature (25 - 30 degrees C) and slow agitation speed (50 - 60 rpm) which could propose vast benefits such as little power utilization and uncomplicated operation. Among six types of adsorption isotherms, Freundlich isotherm showed the best fit with R-2 > 0.997. Pseudo-second order made a better agreement as compare to other kinetic models. The thermodynamic coefficients suggested the passage of Cs+ and Sr2+ ions through the liquid solid boundary is exothermic and spontaneous. The NSC@MS-4A displayed excellent regenerability properties over five repetitive adsorption/ desorption cycles, which specified that as-obtained NSC@MS-4A is a sustainable as well as efficient adsorbent for practical decontamination of radioactive liquid waste.