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A New Benzodithiophene Based Donor-Acceptor pi-Conjugated Polymer for Organic Solar Cells

Authors
Reddy, Saripally SudhakerAryal, Um KantaJin, HyunjungGokulnath, ThavamaniRajalapati, Durga GayathriKranthiraja, KakaraparthiShin, Sung TaeJin, Sung-Ho
Issue Date
2월-2020
Publisher
POLYMER SOC KOREA
Keywords
benzodithiophene based pi-conjugated polymer; octyl side chain; organic solar cell; morphology
Citation
MACROMOLECULAR RESEARCH, v.28, no.2, pp.179 - 183
Indexed
SCIE
SCOPUS
KCI
Journal Title
MACROMOLECULAR RESEARCH
Volume
28
Number
2
Start Page
179
End Page
183
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/57927
DOI
10.1007/s13233-020-8079-z
ISSN
1598-5032
Abstract
A new benzodithiophene based donor-acceptor pi-conjugated polymer (P1) is designed and explored as the photoactive donor for organic solar cells (OSCs). The synthesized donor polymer, P1 displays a wide absorption profile ranging from 300-750 nm with optical band gap of 1.61 eV and moderate ionization potential of -5.30 eV. It has good solubility in non-halogenated and halogenated organic solvents. Next, we fabricated OSCs with P1 by blending with PC71BM, the pristine polymer processed from chlorobenzene showed PCE of 2.79%. Upon addition of external additive diphenyl ether to the blend showed a dramatic improvement in PCE with maximum of 5.33%. DPE tailored the active layer morphology and showed two times higher PCE than pristine films. These results clearly indicate that the new polymer has a great potentiality for enhancing efficiency upon solvent additives, which will provide new routes for the development of new class of polymers for high-performance air-stable OSCs.
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