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Crown ether-appended calix[2]triazolium[2]arene as a macrocyclic receptor for the recognition of the H2PO4- anion

Authors
Cho, JiheeVerwilst, PeterKang, MinjungPan, Jia-LinSharma, AmitHong, Chang SeopKim, Jong SeungKim, Sanghee
Issue Date
21-Jan-2020
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.56, no.7, pp.1038 - 1041
Indexed
SCIE
SCOPUS
Journal Title
CHEMICAL COMMUNICATIONS
Volume
56
Number
7
Start Page
1038
End Page
1041
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/57968
DOI
10.1039/c9cc08906c
ISSN
1359-7345
Abstract
A crown ether-appended calix[2]triazolium[2]arene, which exhibits excellent selectivity for H2PO4- compared to other anions, has been designed and synthesized. The selectivity of the prepared receptor for H2PO4- is caused by the stabilization of H2PO4- by the neighboring triazolium hydrogen bond donors and crown ether hydrogen bond acceptors.
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