Improving electrochemical properties of Lithium-Sulfur batteries by adding a catalyst-embedded interlayer
- Authors
- Cho, Sung Ho; Cho, Sung Man; Bae, Ki Yoon; Kim, Byung Hyuk; Son, Byung Dae; Yoon, Woo Young
- Issue Date
- 20-8월-2019
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Catalyst; Palladium cobalt; Li-S batteries; Pd3Co
- Citation
- ELECTROCHIMICA ACTA, v.315, pp.33 - 40
- Indexed
- SCIE
SCOPUS
- Journal Title
- ELECTROCHIMICA ACTA
- Volume
- 315
- Start Page
- 33
- End Page
- 40
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/63494
- DOI
- 10.1016/j.electacta.2019.05.062
- ISSN
- 0013-4686
- Abstract
- To improve lithium-sulfur (Li-S) battery performance, a new interlayer film of embedded palladium cobalt (Pd3Co) particles is developed. Pd3Co particles on multi-walled carbon nanotubes (MWCNTs) are synthesized by using a modified polyol method. The synthesis of Pd3Co on MWCNTs is confirmed by Xray diffraction, transmission electron microscopy and energy-dispersive X-ray spectroscopy. The interlayer film is prepared through a filtration method using these powders. Li-S batteries with this interlayer have electrochemical properties superior to those with an MWCNT interlayer (0.2, 0.5, and 2.0 C-rates). At 0.2 and 0.5 C-rates, Pd3Co/MWCNT-interlayer cell achieves a better performance than MWCNT-interlayer cell during 200 cycles. In addition, there is a definite performance difference for 2.0 C-rate during 300 cycles. The discharge capacities for the first and 300 cycles for the MWCNT-interlayer cell are 869 mAh g(-1) and 525 mAh g(-1), respectively, whereas those for a Pd3Co/MWCNT-interlayer cell are 953 mAh g(-1) and 752 mAh g(-1), respectively. These improvements are resulted from the catalytic role of Pd3Co, which assists the reaction of polysulfide formation/deformation. (C) 2019 Elsevier Ltd. All rights reserved.
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