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Effective and sustainable Cs+ remediation via exchangeable sodium-ion sites in graphene oxide fibers

Authors
Lee, HeehyeonLee, KyungeunKim, Sang OukLee, Jae-SeungOh, Youngtak
Issue Date
14-8월-2019
Publisher
ROYAL SOC CHEMISTRY
Citation
JOURNAL OF MATERIALS CHEMISTRY A, v.7, no.30, pp.17754 - 17760
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF MATERIALS CHEMISTRY A
Volume
7
Number
30
Start Page
17754
End Page
17760
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/63524
DOI
10.1039/c9ta04027g
ISSN
2050-7488
Abstract
A monovalent sodium-functionalized graphene oxide fiber (Na-GO) structure was synthesized via facile and simple liquid coagulation of a graphene oxide solution. Supported by the stable GO framework, the readily accessible sodium site of this alkali-metal-carbon heterostructure allows effective removal of Cs+ in aqueous medium with a rapid equilibrium time (similar to 30 min) and a large adsorption capacity (220 mg g(-1)). Na-GO possesses physical and chemical integrity in a broad pH range (4-10), and the adsorption behavior is influenced by the hydration radius of the targeting cation, charge effect, pi-M+ interaction, and pH-dependent GO hydrophilicity. In utilizing the chemical potential effect of Na-GO, a simple regeneration process with NaOH solution selectively releases captured Cs+ and replenishes functional sodium sites within the Na-GO structure, providing a rechargeable Cs+ remediation functionality. This study demonstrates the successful adaptation of the alkali-metal-induced reversible ion-exchange principle for a versatile GO fiber structure.
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Lee, Jae Seung
공과대학 (신소재공학부)
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