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Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

Authors
Yi, JigyoungAhn, Hye MiYoon, Jong HoKim, ChealLee, Suk Joong
Issue Date
7-Sep-2018
Publisher
ROYAL SOC CHEMISTRY
Citation
NEW JOURNAL OF CHEMISTRY, v.42, no.17, pp.14067 - 14070
Indexed
SCIE
SCOPUS
Journal Title
NEW JOURNAL OF CHEMISTRY
Volume
42
Number
17
Start Page
14067
End Page
14070
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/73122
DOI
10.1039/c8nj02214c
ISSN
1144-0546
Abstract
A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent immobilization of CuCl2 gave POP-Cu(ii). This new heterogeneous catalyst displayed outstanding olefin oxidation activity compared to its homogeneous analogue, suggesting that the degradation of the homogeneous catalyst was successfully inhibited by site isolation.
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