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Development of Mixed-Cation CsxRb1-xPbX3 Perovskite Quantum Dots and Their Full-Color Film with High Stability and Wide Color Gamut

Authors
Baek, SeungminKim, SunghoonNoh, Jae YoungHeo, Jin HyuckIm, Sang HyukHong, Ki-HaKim, Sang-Wook
Issue Date
6-Aug-2018
Publisher
WILEY-V C H VERLAG GMBH
Keywords
CsxRb1-xPbX3; perovskite quantum dots; improved stability; QD films; cyclic olefin copolymer; white light-emitting diodes
Citation
ADVANCED OPTICAL MATERIALS, v.6, no.15
Indexed
SCIE
SCOPUS
Journal Title
ADVANCED OPTICAL MATERIALS
Volume
6
Number
15
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/73795
DOI
10.1002/adom.201800295
ISSN
2195-1071
Abstract
Mixed-cation CsxRb1-xPbX3 (X = Cl, Br, I) perovskite quantum dots (PeQDs) are developed and show high quantum yields of 93% and 86% for green and blue wavelengths, respectively. The stability is significantly improved under heat, UV, and water aging conditions. These improved properties are explained by the increased defect formation resistance and exciton binding energy with Rb incorporation. Perovskite films are fabricated using CsxRb1-xPbX3 PeQDs and cyclic olefin copolymer. The films have a wide color gamut covering up to 104.15% of the BT.2020-defined color space, with the white light color coordinates of (0.33, 0.32), luminance of 68.86 Cd m(-2), and correlated color temperature of 5299 K at 20 mA.
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