Quinoxaline-Based Wide Band Gap Polymers for Efficient Nonfullerene Organic Solar Cells with Large Open-Circuit Voltages
- Authors
- Yang, Jie; Uddin, Mohammad Afsar; Tang, Yumin; Wang, Yulun; Wang, Yang; Su, Huimin; Gao, Rutian; Chen, Zhi-Kuan; Dai, Junfeng; Woo, Han Young; Guo, Xugang
- Issue Date
- 11-7월-2018
- Publisher
- AMER CHEMICAL SOC
- Keywords
- polymer semiconductors; fluorination; nonfullerene organic solar cells; energy losses; open-circuit voltages
- Citation
- ACS APPLIED MATERIALS & INTERFACES, v.10, no.27, pp.23235 - 23246
- Indexed
- SCIE
SCOPUS
- Journal Title
- ACS APPLIED MATERIALS & INTERFACES
- Volume
- 10
- Number
- 27
- Start Page
- 23235
- End Page
- 23246
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/74354
- DOI
- 10.1021/acsami.8b04432
- ISSN
- 1944-8244
- Abstract
- We present here a series of wide-band-gap (E-g: >1.8 eV) polymer donors by incorporating thiophene-flanked phenylene as an electron-donating unit and quinoxaline as an electron-accepting co-unit to attain large open-circuit voltages (V(oc)s) and short-circuit currents (J(sc)s) in nonfullerene organic solar cells (OSCs). Fluorination was utilized to fine-tailor the energetics of polymer frontier molecular orbitals (FMOs) by replacing a variable number of H atoms on the phenylene moiety with F. It was found that fluorination can effectively modulate the polymer backbone planarity through intramolecular noncovalent S...F and/or H...F interactions. Polymers (P2-P4) show an improved molecular packing with a favorable face-on orientation compared to their nonfluorinated analogue (P1), which is critical to charge carrier transport and collection. When mixed with IDIC, a nonfullerene acceptor, P3 with two F atoms, achieves a remarkable V-oc of 1.00 V and a large J(sc) of 15.99 mA/cm(2), simultaneously, yielding a power-conversion efficiency (PCE) of 9.7%. Notably, the 1.00 V V-oc is among the largest values in the IDIC-based OSCs, leading to a small energy loss (E-loss: 0.62 eV) while maintaining a large PCE. The P3:IDIC blend shows an efficient exciton dissociation through hole transfer even under a small energy offset of 0.16 eV. Further fluorination leads to the polymer P4 with increased chain-twisting and mismatched FMO levels with IDIC, showing the lowest PCE of 2.93%. The results demonstrate that quinoxaline-based copolymers are promising donors for efficient OSCs and the fluorination needs to be fine-adjusted to optimize the interchain packing and physicochemical properties of polymers. Additionally, the structure property correlations from this work provide useful insights for developing wide-band-gap polymers with low-lying highest occupied molecular orbitals to minimize E-loss, and maximize V-oc in nonfullerene OSCs for efficient power conversion.
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