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Achieving 14.4% Alcohol-Based Solution-Processed Cu(In,Ga)(S,Se)(2) Thin Film Solar Cell through Interface Engineering

Authors
Park, Gi SoonChu, Van BenKim, Byoung WooKim, Dong-WookOh, Hyung-SukHwang, Yun JeongMin, Byoung Koun
Issue Date
28-3월-2018
Publisher
AMER CHEMICAL SOC
Keywords
CIGS thin-film solar cell; solution-process; grain growth; p-n junction; interface engineering; band alignment
Citation
ACS APPLIED MATERIALS & INTERFACES, v.10, no.12, pp.9894 - 9899
Indexed
SCIE
SCOPUS
Journal Title
ACS APPLIED MATERIALS & INTERFACES
Volume
10
Number
12
Start Page
9894
End Page
9899
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/76681
DOI
10.1021/acsami.8b00526
ISSN
1944-8244
Abstract
An optimization of band alignment at the p-n junction interface is realized on alcohol-based solution-processed Cu(In,Ga)(S,Se)(2) (CIGS) thin film solar cells, achieving a power-conversion-efficiency (PCE) of 14.4%. To obtain a CIGS thin film suitable for interface engineering, we designed a novel "3-step chalcogenization process" for Cu2-xSe-derived grain growth and a double band gap grading structure. Considering S-rich surface of the CIGS thin film, an alternative ternary (Cd,Zn)S buffer layer is adopted to build favorable "spike" type conduction band alignment instead of "cliff" type. Suppression of interface recombination is elucidated by comparing recombination activation energies using a dark J-V-T analysis.
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