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Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged M-II (M = Mn, Ni) coordination polymers
- Authors
- Lim, Kwang Soo; Song, Jeong Hwa; Kang, Dong Won; Kang, Minjung; Eom, Sunhwi; Koh, Eui Kwan; Hong, Chang Seop
- Issue Date
- 21-Jan-2018
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- DALTON TRANSACTIONS, v.47, no.3, pp.845 - 851
- Indexed
- SCIE
SCOPUS
- Journal Title
- DALTON TRANSACTIONS
- Volume
- 47
- Number
- 3
- Start Page
- 845
- End Page
- 851
- ISSN
- 1477-9226
- Abstract
- M-II (M = Mn, Ni) coordination frameworks, singly linked by end-on azide ligands, were prepared by employing the long, flexible spacer ligand, p-XBP4. These two-dimensional layer structures underwent reversible crystal-to-amorphous phase transformations during the hydration-dehydration process. Moreover, the magnetic nature changes from antiferromagnetic to ferromagnetic coupling when moving from Mn to Ni.
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Collections - College of Science > Department of Chemistry > 1. Journal Articles
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