Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets
DC Field | Value | Language |
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dc.contributor.author | Lim, Kwang Soo | - |
dc.contributor.author | Baldovi, Jose J. | - |
dc.contributor.author | Jiang, ShangDa | - |
dc.contributor.author | Koo, Bong Ho | - |
dc.contributor.author | Kang, Dong Won | - |
dc.contributor.author | Lee, Woo Ram | - |
dc.contributor.author | Koh, Eui Kwan | - |
dc.contributor.author | Gaita-Arino, Alejandro | - |
dc.contributor.author | Coronado, Eugenio | - |
dc.contributor.author | Slota, Michael | - |
dc.contributor.author | Bogani, Lapo | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.date.accessioned | 2021-09-03T06:21:59Z | - |
dc.date.available | 2021-09-03T06:21:59Z | - |
dc.date.created | 2021-06-16 | - |
dc.date.issued | 2017-05-01 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/83501 | - |
dc.description.abstract | Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-field computational tools (SIMPRE and CONDON codes) allows us to explain the static behavior of these systems in detail. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | SINGLE-ION MAGNETS | - |
dc.subject | SPIN QUBITS | - |
dc.subject | RELAXATION | - |
dc.subject | ANISOTROPY | - |
dc.subject | COMPLEXES | - |
dc.subject | SYMMETRY | - |
dc.subject | DY(III) | - |
dc.subject | BARRIER | - |
dc.subject | CROSSOVER | - |
dc.subject | COHERENCE | - |
dc.title | Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.identifier.doi | 10.1021/acs.inorgchem.6b03118 | - |
dc.identifier.scopusid | 2-s2.0-85018984560 | - |
dc.identifier.wosid | 000400633200017 | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.56, no.9, pp.4911 - 4917 | - |
dc.relation.isPartOf | INORGANIC CHEMISTRY | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 56 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 4911 | - |
dc.citation.endPage | 4917 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | SINGLE-ION MAGNETS | - |
dc.subject.keywordPlus | SPIN QUBITS | - |
dc.subject.keywordPlus | RELAXATION | - |
dc.subject.keywordPlus | ANISOTROPY | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | SYMMETRY | - |
dc.subject.keywordPlus | DY(III) | - |
dc.subject.keywordPlus | BARRIER | - |
dc.subject.keywordPlus | CROSSOVER | - |
dc.subject.keywordPlus | COHERENCE | - |
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