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Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets

Authors
Lim, Kwang SooBaldovi, Jose J.Jiang, ShangDaKoo, Bong HoKang, Dong WonLee, Woo RamKoh, Eui KwanGaita-Arino, AlejandroCoronado, EugenioSlota, MichaelBogani, LapoHong, Chang Seop
Issue Date
1-5월-2017
Publisher
AMER CHEMICAL SOC
Citation
INORGANIC CHEMISTRY, v.56, no.9, pp.4911 - 4917
Indexed
SCIE
SCOPUS
Journal Title
INORGANIC CHEMISTRY
Volume
56
Number
9
Start Page
4911
End Page
4917
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/83501
DOI
10.1021/acs.inorgchem.6b03118
ISSN
0020-1669
Abstract
Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-field computational tools (SIMPRE and CONDON codes) allows us to explain the static behavior of these systems in detail.
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