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Development of Monolithic Catalyst System with Co-Ru-Zr for CO2 (dry) Reforming of Methane : Enhanced Coke ToleranceDevelopment of Monolithic Catalyst System with Co-Ru-Zr for CO2 (dry) Reforming of Methane : Enhanced Coke Tolerance

Other Titles
Development of Monolithic Catalyst System with Co-Ru-Zr for CO2 (dry) Reforming of Methane : Enhanced Coke Tolerance
Authors
김효진유영우허일정장태선홍지숙이기봉서정권
Issue Date
2017
Publisher
한국청정기술학회
Keywords
CO2 reforming; Cobalt-ruthenium-zirconium; Monolith catalysts; Coking; Catalyst durability
Citation
Clean Technology, v.23, no.3, pp.314 - 324
Indexed
KCI
Journal Title
Clean Technology
Volume
23
Number
3
Start Page
314
End Page
324
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/86193
ISSN
1598-9712
Abstract
To verify the viability of Co, Ru and Zr-based catalyst for CO2 (dry) reforming reaction, catalysts were fabricated using cordierite, silicon carbide and rota monolithic substrates, and they were compared with the conventional Co-Ru-Zr/SiO2 catalyst in terms of performance and durability. Cordierite monolith was showed high activity with the least amount of active component. In addition, when Cordierite monolith was coated with Co-Ru-Zr in various ways, most excellent performance was showed at a precursor solution coating method. In particular, when 0.9 wt% Co-Ru-Zr/Cordierite was used for reaction, it was observed that 95% CO2 conversion was maintained for 300 h at 900 ℃.
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