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Transition-Metal-Free Decarboxylative Coupling Reactions for the Synthesis of Propargyl Alcohols

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dc.contributor.authorIrudayanathan, Francis Mariaraj-
dc.contributor.authorKim, Jimin-
dc.contributor.authorSong, Kwang Ho-
dc.contributor.authorLee, Sunwoo-
dc.date.accessioned2021-09-03T20:22:46Z-
dc.date.available2021-09-03T20:22:46Z-
dc.date.created2021-06-16-
dc.date.issued2016-09-
dc.identifier.issn2193-5807-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/87616-
dc.description.abstractPropargyl alcohols have been directly synthesized by decarboxylative coupling reactions with an alkynyl carboxylic acid and an aldehyde/ketone in the absence of a transition-metal catalyst. When the decarboxylative coupling reaction was conducted with Cs2CO3 in DMSO, the desired propargyl alcohols were formed in good yield. In addition, the reactions with 2,2,2-trifluoroacetophenone and aryl alkynyl carboxylic acids gave trifluoromethylated propargyl alcohols.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectTRIFLUOROMETHYL KETONES-
dc.subjectCATALYTIC ALKYNYLATION-
dc.subjectCARBOXYLIC-ACIDS-
dc.subjectTERMINAL ALKYNES-
dc.subjectALDEHYDES-
dc.subjectEFFICIENT-
dc.subjectAMINES-
dc.subjectWATER-
dc.subjectNANOPARTICLES-
dc.subjectHETEROCYCLES-
dc.titleTransition-Metal-Free Decarboxylative Coupling Reactions for the Synthesis of Propargyl Alcohols-
dc.typeArticle-
dc.contributor.affiliatedAuthorSong, Kwang Ho-
dc.identifier.doi10.1002/ajoc.201600265-
dc.identifier.scopusid2-s2.0-84987945039-
dc.identifier.wosid000383686500011-
dc.identifier.bibliographicCitationASIAN JOURNAL OF ORGANIC CHEMISTRY, v.5, no.9, pp.1148 - 1154-
dc.relation.isPartOfASIAN JOURNAL OF ORGANIC CHEMISTRY-
dc.citation.titleASIAN JOURNAL OF ORGANIC CHEMISTRY-
dc.citation.volume5-
dc.citation.number9-
dc.citation.startPage1148-
dc.citation.endPage1154-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusTRIFLUOROMETHYL KETONES-
dc.subject.keywordPlusCATALYTIC ALKYNYLATION-
dc.subject.keywordPlusCARBOXYLIC-ACIDS-
dc.subject.keywordPlusTERMINAL ALKYNES-
dc.subject.keywordPlusALDEHYDES-
dc.subject.keywordPlusEFFICIENT-
dc.subject.keywordPlusAMINES-
dc.subject.keywordPlusWATER-
dc.subject.keywordPlusNANOPARTICLES-
dc.subject.keywordPlusHETEROCYCLES-
dc.subject.keywordAuthoraldehydes-
dc.subject.keywordAuthoralkynyl carboxylic acid-
dc.subject.keywordAuthordecarboxylative coupling-
dc.subject.keywordAuthorketones-
dc.subject.keywordAuthorpropargyl alcohol-
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