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Enhanced Oxidation Stability of VO2 by Coating SiO2 Layer for Smart Window Applications

Authors
Shin, Jee HyeKim, Hee JungLee, Ki BongYoo, Jung Whan
Issue Date
Jun-2016
Publisher
AMER SCIENTIFIC PUBLISHERS
Keywords
Oxidation Stability; Vanadium Dioxide; Phase Transition Nanoparticle; Core-Shell Structure; Energy Efficiency
Citation
NANOSCIENCE AND NANOTECHNOLOGY LETTERS, v.8, no.6, pp.510 - 513
Indexed
SCIE
SCOPUS
Journal Title
NANOSCIENCE AND NANOTECHNOLOGY LETTERS
Volume
8
Number
6
Start Page
510
End Page
513
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/88528
DOI
10.1166/nnl.2016.2065
ISSN
1941-4900
Abstract
SiO2-coated W-VO2(M) nanoparticles were synthesized by a precipitation method and then modified with tetraethylorthosilicate as a precursor using the Stober process, to enhance oxidation stability. W-VO2(M) nanoparticles were uniformly coated with a SiO2 layer approximately 25 nm in thickness. Based on XRD and DSC characterization, the crystal structure and phase transition temperature of SiO2-coated W-VO2(M) are almost the same as before SiO2 coating. Upon exposure to 80% water vapor pressure at 80 degrees C, the coated nanoparticles maintain their structure, phase transition temperature, and morphology for a longtime compared to uncoated W-VO2(M) particles, and show improved oxidation stability.
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