Na-ion Storage Performances of FeSex and Fe2O3 Hollow Nanoparticles-Decorated Reduced Graphene Oxide Balls prepared by Nanoscale Kirkendall Diffusion Process
- Authors
- Park, Gi Dae; Cho, Jung Sang; Lee, Jung-Kul; Kang, Yun Chan
- Issue Date
- 29-2월-2016
- Publisher
- NATURE PUBLISHING GROUP
- Citation
- SCIENTIFIC REPORTS, v.6
- Indexed
- SCIE
SCOPUS
- Journal Title
- SCIENTIFIC REPORTS
- Volume
- 6
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/89466
- DOI
- 10.1038/srep22432
- ISSN
- 2045-2322
- Abstract
- Uniquely structured FeSex-reduced graphene oxide (rGO) composite powders, in which hollow FeSex nanoparticles are uniformly distributed throughout the rGO matrix, were prepared by spray pyrolysis applying the nanoscale Kirkendall diffusion process. Iron oxide-rGO composite powders were transformed into FeSex-rGO composite powders by a two-step post-treatment process. Metallic Fe nanocrystals formed during the first-step post-treatment process were transformed into hollow FeSex nanoparticles during the selenization process. The FeSex-rGO composite powders had mixed crystal structures of FeSe and FeSe2 phases. A rGO content of 33% was estimated from the TG analysis of the FeSex-rGO composite powders. The FeSex-rGO composite powders had superior sodium-ion storage properties compared to those of the Fe2O3-rGO composite powders with similar morphological characteristics. The discharge capacities of the FeSex- and Fe2O3-rGO composite powders for the 200th cycle at a constant current density of 0.3 A g(-1) were 434 and 174 mA h g(-1), respectively. The FeSex-rGO composite powders had a high discharge capacity of 311 mA h g(-1) for the 1000th cycle at a high current density of 1 A g(-1).
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Engineering > Department of Materials Science and Engineering > 1. Journal Articles
![qrcode](https://api.qrserver.com/v1/create-qr-code/?size=55x55&data=https://scholar.korea.ac.kr/handle/2021.sw.korea/89466)
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.