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A mild, efficient, and selective procedure for the deoxygenation of sulfoxides with the TaCl5/indium system
- Authors
- Yoo, Byung Woo; Lee, Min Kyung; Yoon, Cheol Min
- Issue Date
- 2016
- Publisher
- TAYLOR & FRANCIS LTD
- Keywords
- Deoxygenation; sulfoxide; sulfide; tantalum(V) chloride; indium
- Citation
- PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, v.191, no.6, pp.807 - 810
- Indexed
- SCIE
SCOPUS
- Volume
- 191
- Number
- 6
- Start Page
- 807
- End Page
- 810
- ISSN
- 1042-6507
- Abstract
- The TaCl5/In system was found to be a new reagent for reducing a wide range of structurally diverse sulfoxides to the corresponding sulfides with high yields under mild conditions. This protocol is chemoselective and tolerates several functional groups, such as Br, Cl, OCH3, CHO, and CH = CH2.
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