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A facile and efficient procedure for the deoxygenation of sulfoxides to sulfides with the HfCl4/Zn system
- Authors
- Yoo, Byung Woo; Yu, Bo Ran; Yoon, Cheol Min
- Issue Date
- 4-7월-2015
- Publisher
- TAYLOR & FRANCIS LTD
- Keywords
- sulfoxide; zinc; hafnium(IV) chloride; sulfide; deoxygenation
- Citation
- JOURNAL OF SULFUR CHEMISTRY, v.36, no.4, pp.358 - 363
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF SULFUR CHEMISTRY
- Volume
- 36
- Number
- 4
- Start Page
- 358
- End Page
- 363
- ISSN
- 1741-5993
- Abstract
- Treatment of sulfoxides with the HfCl4/Zn system in acetonitrile at room temperature has been shown to provide the corresponding sulfides in high yields. This new methodology is highly chemoselective, tolerating several functional groups such as -Br, -Cl, -OCH3, -CHO and double bond.
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