Semiconducting pi-extended porphyrin dimer and its characteristics in OFET and OPVC
- Authors
- Park, Woo Jea; Chae, Seung Hyun; Shin, Jicheol; Choi, Dong Hoon; Lee, Suk Joong
- Issue Date
- 7월-2015
- Publisher
- ELSEVIER SCIENCE SA
- Keywords
- Field-effect transistors; Porphyrins; Thin films; Semiconductors; pi-pi interactions
- Citation
- SYNTHETIC METALS, v.205, pp.206 - 211
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNTHETIC METALS
- Volume
- 205
- Start Page
- 206
- End Page
- 211
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/93153
- DOI
- 10.1016/j.synthmet.2015.04.017
- ISSN
- 0379-6779
- Abstract
- Porphyrin is considered as one of the best candidates for various organic electronic devices, due to its molecular planarity and pi-conjugation. Particularly, for the good performing OFETs based on porphyrin derivatives, they should have high crystallinity and close pi-pi stacking distance in solid state. However, pi-extended dimeric porphyrin has never been introduced as a charge transport layer in OFETs. In this regard, we report here on the design and synthesis of new solution processable semiconducting pi-extended porphyrin dimer (PD-1), and its OFET and OPVC characteristics. Due to strong pi-pi. interactions, PD-1 showed high crystallinity in film state which displayed an excellent electrical characteristics with high hole mobility of 0.026 cm(2)/Vs and high current on off ratio of >10(5), when the device was fabricated in the mixed solvents of toluene and THF. This mobility is 1000 times better than that of a device fabricated from a solution either THF or toluene exclusively. Furthermore, the photovoltaic performance of PD-1 device shows a PCE of 0.58%. The effective pi-conjugation and molecular planarity of pi-extended dimeric porphyrin (PD-1) can lead to significant changes in the electrical characteristics of the devices. (C) 2015 Elsevier B.V. All rights reserved.
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