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Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores

Authors
Dozova, NadiaKumar, RajeshPradhan, TuhinLacombat, FabienValeur, BernardKim, Jong SeungPlaza, Pascal
Issue Date
2015
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.51, no.80, pp.14859 - 14861
Indexed
SCIE
SCOPUS
Journal Title
CHEMICAL COMMUNICATIONS
Volume
51
Number
80
Start Page
14859
End Page
14861
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/96176
DOI
10.1039/c5cc06054k
ISSN
1359-7345
Abstract
We present a new molecular shuttle, consisting of a calixarene core attached to two different photoactive centers, DCM and DMABN. We show that a K+ ion bound to the DCM-grafted crown is translocated towards the other site of the molecule upon photoexcitation, but not released to the bulk.
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