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Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO2 removal
- Authors
- Park, Sunghwan; Lee, Albert S.; Do, Yu Seong; Hwang, Seung Sang; Lee, Young Moo; Lee, Jung-Hyun; Lee, Jong Suk
- Issue Date
- 2015
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- CHEMICAL COMMUNICATIONS, v.51, no.83, pp.15308 - 15311
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMICAL COMMUNICATIONS
- Volume
- 51
- Number
- 83
- Start Page
- 15308
- End Page
- 15311
- ISSN
- 1359-7345
- Abstract
- Poly(methoxy(polyethyleneoxy)propyl-co-methacryloxypropyl)silsesquioxane membranes with different copolymer ratios were successfully fabricated via UV-induced crosslinking with mechanical stability. By selectively introducing polyethylene oxide (PEO) groups covalently bound to the ladder-structured polysilsesquioxane, we effectively suppressed the PEO crystallization, allowing for excellent CO2/H-2 and CO2/N-2 separation under single as well as mixed gas conditions.
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Related Researcher
- LEE, Jung hyun
- College of Engineering (Department of Chemical and Biological Engineering)