Chiral environment of catalytic sites in the chiral metal-organic frameworks
- Authors
- Lee, Misun; Shin, Sung Min; Jeong, Nakcheol; Thallapally, Praveen K.
- Issue Date
- 2015
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- DALTON TRANSACTIONS, v.44, no.20, pp.9349 - 9352
- Indexed
- SCIE
SCOPUS
- Journal Title
- DALTON TRANSACTIONS
- Volume
- 44
- Number
- 20
- Start Page
- 9349
- End Page
- 9352
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/96243
- DOI
- 10.1039/c5dt01322d
- ISSN
- 1477-9226
- Abstract
- Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e. g., that of the surface is anisotropic, whereas that of the interior is isotropic.
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