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Highly flexible transparent self-healing composite based on electrospun core-shell nanofibers produced by coaxial electrospinning for anti-corrosion and electrical insulation

Authors
An, SeongpilLiou, MinhoSong, Kyo YongJo, Hong SeokLee, Min WookAl-Deyab, Salem S.Yarin, Alexander L.Yoon, Sam S.
Issue Date
2015
Publisher
ROYAL SOC CHEMISTRY
Citation
NANOSCALE, v.7, no.42, pp.17778 - 17785
Indexed
SCIE
SCOPUS
Journal Title
NANOSCALE
Volume
7
Number
42
Start Page
17778
End Page
17785
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/96336
DOI
10.1039/c5nr04551g
ISSN
2040-3364
Abstract
Coaxial electrospinning was used to fabricate two types of core-shell fibers: the first type with liquid resin monomer in the core and polyacrylonitrile in the shell, and the second type with liquid curing agent in the core and polyacrylonitrile in the shell. These two types of core-shell fibers were mutually entangled and embedded into two flexible transparent matrices thus forming transparent flexible self-healing composite materials. Such materials could be formed before only using emulsion electrospinning, rather than coaxial electrospinning. The self-healing properties of such materials are associated with release of healing agents (resin monomer and cure) from nanofiber cores in damaged locations with the subsequent polymerization reaction filing the micro-crack with polydimethylsiloxane. Transparency of these materials is measured and the anti-corrosive protection provided by them is demonstrated in electrochemical experiments.
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